<b>Make the filling layers:</b> Line a greased 9-inch square pan with parchment paper (two sheets overlapping to make a plus-sign).
Break or chop the chocolate into small pieces. Melt the chocolate (130g) in the microwave in short increments, stopping to stir. Stop when it's almost melted so the rest melts from stirring.
Pour it into the prepared pan. Spread it out into one even layer then set it in the freezer for 15-20 minutes to firm up.
Make the peanut butter layer by stirring together the peanut butter, salt, and powdered sugar. Put it in the microwave for about 20-30 seconds once or twice, stirring, so the peanut butter is easier to spread (BUT don't get it ot hot or it will melt the chocolate).
Spread it in an even layer over the firm chocolate and set it back in the freezer for 20-30 minutes.
If you choose to do a second layer of chocolate (see notes; 130g), then repeat the first step and chill it.
<b>Make the brownies:</b> Preheat the oven to 350 F and make the brownie batter.
In a large heat-proof bowl, melt the butter almost all the way, then add the sugar and whisk it in.
Return to the microwave for another 30 seconds, then add the vanilla and salt.
Whisk the mixture very well, for about 2 FULL minutes.
Add the cocoa and whisk well. The mixture will be loose at first, then start to firm up as you whisk.
Add the eggs, whisking for about 3 minutes.
Add the flour and chopped chocolate, and use a rubber spatula to combine.
<b>Assemble & bake:</b> Remove the chilled chocolate peanut butter layer from the freezer and out of the pan, keeping the parchment paper in the pan.
Pour two-thirds of the brownie batter into the pan in an even layer. Place the chocolate peanut butter block on top, then pour over the rest of the brownie batter. Smooth it out so it reaches the corners.
Bake for about 35-45 minutes, until the middle is puffing up. Look at the center of the brownie, when it’s puffy it signals the eggs in the batter have cooked.
Allow to cool fully before slicing (I even put them temporarily in the fridge, not for a long time but like 30 minutes). If you freeze them the layers will slice very cleanly and you’ll get clear layers, if that's important.